英文论文
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文献类型
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Article
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题名
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Crucial support effect on the durability of Pt/MgAl2O4 for partial oxidation of methane to syngas
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作者
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Wang, Fen; Li, Wei-Zhen; Lin, Jing-Dong; Chen, Zhi-Qiang; Wang, Yong
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作者单位
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[Wang, Fen; Lin, Jing-Dong; Wang, Yong] Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, Natl Engn Lab Green Chem Prod Alcohols Ethers Est, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China; [Wang, Fen; Li, Wei-Zhen; Chen, Zhi-Qiang] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China; [Wang, Yong] Washington State Univ, Voiland Sch Chem Engn & Bioengn, Pullman, WA 99164 USA
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通讯作者地址
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Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China.
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Email
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ResearchID
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ORCID
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期刊名称
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APPLIED CATALYSIS B-ENVIRONMENTAL
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出版社
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ELSEVIER SCIENCE BV
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ISSN
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0926-3373
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出版信息
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2018-09-05, 231:292-298.
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JCR
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1
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影响因子
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14.229
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ISBN
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基金
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National Key R&D Program of China [2016YFA0202801]; National Natural Science Foundation of China [21403213, 91545114, 21376236]; Strategic Priority Research Program of the Chinese Academy of Sciences [XDB17020100]; "Hundred Talents Programme" of the Chinese Academy of Sciences; Department of Science and Technology of Liaoning province [2015020086-101]
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会议名称
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会议地点
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会议开始日期
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会议结束日期
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关键词
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CATALYTIC PARTIAL OXIDATION; SYNTHESIS GAS; NI/AL2O3 CATALYST; NANOPARTICLES; NI; MECHANISM; HYDROGEN; MGAL2O4; RH
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摘要
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Catalyst durability is one of the major problems hindering the commercialization of partial oxidation of methane (POM) for syngas production. We report that a Pt/MgAl2O4-HS catalyst with the MgAl2O4-HS support being synthesized via hydrolysis solvothermal (HS) method demonstrates high stability for POM during a 500 h life testing at 900 degrees C without detectable coke formation, while a Pt/MgAl2O4-CP counterpart in which MgAl2O4 was prepared by an optimized co-precipitation (CP) method exhibits continuous deactivation accompanied by coking. Using a suite of characterizations lncluidng BET, H-2 chemisorption, XRD, STEM, TEM, TG/DTA and TPD of NH3 and CO2, we reveal that the high catalytic durability of the Pt/MgAl2O4-HS is due to the spinel surface of MgAl2O4 HS that can efficiently stabilize Pt against sintering. The Pt/MgAl2O4-CP, however, has defect Al2O3 or MgO-like species on the MgAl2O4-CP surface, inhibiting its capability to stabilize Pt. We confirm that the POM reaction undergoes a combustion-reforming pathway by monitoring the temperatures and gaseous product compositions along the catalyst bed. These results provide guidance for rational design of a longevity catalyst for POM process.
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一级学科
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Chemistry, Physical; Engineering, Environmental; Engineering, Chemical
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WOS入藏号
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WOS:000430762300031
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EI收录号
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20181705110377
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DOI
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10.1016/j.apcatb.2018.03.018
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ESI
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CHEMISTRY
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收录于
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SCIE, EI
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