英文论文
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文献类型
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Journal article (JA)
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题名
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Catalytic transfer hydrogenation of biomass-derived 5-hydroxymethylfurfural into 2,5-dihydroxymethylfuran over magnetic zirconium-based coordination polymer
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作者
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Hu, Lei (1); Li, Ting (1); Xu, Jiaxing (1); He, Aiyong (1); Tang, Xing (2); Chu, Xiaozhong (1); Xu, Jiming (1)
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作者单位
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(1) Jiangsu Key Laboratory for Biomass-based Energy and Enzyme Technology, Jiangsu Collaborative Innovation Center of Regional Modern Agriculture & Environmental Protection, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian; 223300, China (2) College of Energy, Xiamen University, Xiamen; 361102, China
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通讯作者地址
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Huaiyin Normal Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Biomass Based Energy & Enzyme Tec, Jiangsu Collaborat Innovat Ctr Reg Modern Agr & E, Huaian 223300, Peoples R China.
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Email
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ResearchID
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ORCID
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期刊名称
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Chemical Engineering Journal
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出版社
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Elsevier B.V.
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ISSN
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1385-8947
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出版信息
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2018-11-15, 352:110-119.
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JCR
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1
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影响因子
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8.355
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ISBN
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基金
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Natural Science Foundation of Jiangsu Province [BK20150413]; National Natural Science Foundation of China [21506071]; Natural Science Foundation of the Higher Education Institutions of Jiangsu Province [16KJA530001]; Special Foundation for Young Talents of Jiangsu Collaborative Innovation Center of Regional Modern Agriculture & Environmental Protection [HSXT2-316]
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会议名称
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会议地点
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会议开始日期
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会议结束日期
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关键词
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Biomass; Carbonyl compounds; Catalyst activity; Chlorine compounds; Coordination reactions; Hydrogenation; Iron oxides; Magnetite; Polymers; Pore size; Selective catalytic reduction
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摘要
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Catalytic transfer hydrogenation (CTH) of 5-hydroxymethylfurfural (HMF) into 2,5-dihydroxymethylfuran (DHMF) via Meerwein-Ponndorf-Verley (MPV) reaction is a very important pathway for the effective utilization of biomass. In this process, the development of high-efficiency heterogeneous catalysts is the key, which has attracted increasing attention in recent years. Herein, a zirconium-based organic-inorganic coordination polymer with magnetic property (MZCCP) was successfully prepared by the reaction of zirconium tetrachloride (ZrCl4) and cyanuric acid (CA) on the surface of ferriferrous oxide (Fe3O4). As expected, MZCCP was an excellent acid-base bifunctional catalyst with the higher acid-base strength and content and the proper acid-base ratio as well as the appropriate surface area and pore size, and so it showed high catalytic activity for the CTH of HMF into DHMF with satisfactory yield of 93.4% at a moderate reaction temperature of 140 °C for 5 h in the presence of 2-butanol, which simultaneously acted as hydrogen donor and reaction medium. Furthermore, it should be specially noted that MZCCP could be easily separated from the reaction mixture by using an outer magnet, and repetitively used at least five reaction runs without an obvious loss of activity. More importantly, MZCCP could also be applicable for the CTH of 5-methylfurfural (MF), furfural (FF), cyclohexanone (CHN), levulinic acid (LA) and ethyl levulinate (EL) into the corresponding products in high yields, indicating that it possessed a superior universality for the selective reduction of various biomass-derived carbonyl compounds. ? 2018 Elsevier B.V.
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一级学科
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Engineering, Environmental; Engineering, Chemical
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WOS入藏号
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WOS:000444001900013
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EI收录号
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20182705404530
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DOI
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10.1016/j.cej.2018.07.007
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ESI
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ENGINEERING
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收录于
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SCIE, EI
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