英文论文
-
文献类型
-
Journal article (JA)
-
题名
-
Revealing unconventional host-guest complexation at nanostructured interface by surface-enhanced Raman spectroscopy
-
作者
-
Chen, Gan-Yu; Sun, Yi-Bin; Shi, Pei-Chen; Liu, Tao; Li, Zhi-Hao; Luo, Si-Heng; Wang, Xin-Chang; Cao, Xiao-Yu; Ren, Bin; Liu, Guo-Kun; Yang, Liu-Lin; Tian, Zhong-Qun
-
作者单位
-
[Chen, Gan-Yu; Sun, Yi-Bin; Shi, Pei-Chen; Liu, Tao; Li, Zhi-Hao; Luo, Si-Heng; Cao, Xiao-Yu; Ren, Bin; Yang, Liu-Lin; Tian, Zhong-Qun] Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Energy Mat iChEM, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China. [Liu, Tao; Luo, Si-Heng; Liu, Guo-Kun] Xiamen Univ, Coll Environm & Ecol, Ctr Marine Environm Chem & Toxicol, State Key Lab Marine Environm Sci,Fujian Prov Key, Xiamen 361102, Peoples R China. [Wang, Xin-Chang] Xiamen Univ, Natl Model Microelect Coll, Sch Elect Sci & Engn, Xiamen 361005, Peoples R China. [Cao, Xiao-Yu] Xiamen Univ, Key Lab Chem Biol Fujian Prov, Xiamen 361005, Peoples R China.
-
通讯作者地址
-
; Xiamen Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Chem Energy Mat iChEM, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China.; Xiamen Univ, Coll Environm & Ecol, Ctr Marine Environm Chem & Toxicol, State Key Lab Marine Environm Sci,Fujian Prov Key, Xiamen 361102, Peoples R China.
-
Email
-
guokunliu@xmu.edu.cn; llyang@xmu.edu.cn; zqtian@xmu.edu.cn
-
ResearchID
-
-
ORCID
-
-
期刊名称
-
Light: Science and Applications
-
出版社
-
Springer Nature
-
ISSN
-
2095-5545
-
出版信息
-
2021-12, 10 (1):.
-
JCR
-
1
-
影响因子
-
15.165
-
ISBN
-
-
基金
-
NSFCNational Natural Science Foundation of China (NSFC) [41876099, 91427304, 91227111, 21722304, 21971216]; Xiamen Science and Technology Project [3502Z20183002]
-
会议名称
-
-
会议地点
-
-
会议开始日期
-
-
会议结束日期
-
-
关键词
-
Complexation; Gold metallography; Light transmission; Nanostructured materials; Negative ions; Raman spectroscopy
-
摘要
-
Interfacial host-guest complexation offers a versatile way to functionalize nanomaterials. However, the complicated interfacial environment and trace amounts of components present at the interface make the study of interfacial complexation very difficult. Herein, taking the advantages of near-single-molecule level sensitivity and molecular fingerprint of surface-enhanced Raman spectroscopy (SERS), we reveal that a cooperative effect between cucurbit[7]uril (CB[7]) and methyl viologen (MV(2+)2I(-)) in aggregating Au NPs originates from the cooperative adsorption of halide counter anions I-, MV2+, and CB[7] on Au NPs surface. Moreover, similar SERS peak shifts in the control experiments using CB[n]s but with smaller cavity sizes suggested the occurrence of the same guest complexations among CB[5], CB[6], and CB[7] with MV2+. Hence, an unconventional exclusive complexation model is proposed between CB[7] and MV2+ on the surface of Au NPs, distinct from the well-known 1:1 inclusion complexation model in aqueous solutions. In summary, new insights into the fundamental understanding of host-guest interactions at nanostructured interfaces were obtained by SERS, which might be useful for applications related to host-guest chemistry in engineered nanomaterials.
-
一级学科
-
Optics
-
WOS入藏号
-
WOS:000641640600001
-
EI收录号
-
20211710249938
-
DOI
-
10.1038/s41377-021-00526-5
-
ESI
-
-
收录于
-
SCIE, EI
-
返回