Unusual Kinetics Induced by Ligands in Rhodium(III)-Catalyzed Dehydrogenative Olefination Reactions

Well-Defined Rhodium Diphenylphosphine Oxide Complexes Relevant to Rh(III)-Catalyzed Aryl C-H Phosphorylation

Cyclometalated Platinum(II) Metallomesogens Based on Half-Disc-Shaped beta-Diketonate Ligands with Hexacatenar: Crystal Structures, Mesophase Properties, and Semiconductor Devices

Investigating the non-classical M-H-2 bonding in OsClH3(PPh3)(3)

Ruthenium-Catalyzed Oxygenative Transformation of Terminal Propargyl Alcohols to Metheyleneketenes via Allenylidene Intermediates: Synthesis of alpha,beta-Unsaturated Carboxylic Acid Derivatives

Extension of the Simmons-Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with sigma-aromaticity

Trisulfur radical anion-triggered stitching thienannulation: rapid access to largely pi-extended thienoacenes

Scalable Rhodium(III)-Catalyzed Aryl C-H Phosphorylation Enabled by Anodic Oxidation Induced Reductive Elimination

Dual Effects of Cyclopentadienyl Ligands on Rh(III)-Catalyzed Dehydrogenative Arylation of Electron-Rich Alkenes

Reactivity of Ruthenium Allenylidene Complexes with Hydrazines: Formation of Acrylonitrile Complexes

Rh(III)-Catalyzed regio- and stereoselective bisindolylation of vinyl acetate: an efficient approach toward (E)-1,2-bis(2-indolyl)ethenes

Efficient endo Cycloisomerization of Terminal Alkynols Catalyzed by a New Ruthenium Complex with 8-(Diphenylphosphino)quinoline Ligand and Mechanistic Investigation

Isolation of an Eleven-Atom Polydentate Carbon-Chain Chelate Obtained by Cycloaddition of a Cyclic Osmium Carbyne with an Alkyne

Ruthenium and Osmium Germyl Complexes Derived from the Reactions of MXCl(PPh3)(3) (M = Ru, Os; X = Cl, H) with Terphenylchlorogermylene (C6H3-2,6-Trip(2))GeCl (Trip=2,4,6-iPr(3)C(6)H(2))

beta-Diketiminato-Germylene Complexes of Carbonyl Ruthenium: Synthesis, Structure, and Reactivity

K2S2O8-Promoted Direct C-H Phosphorylation of (Benzo)thiazoles

Regioselective Direct C3-Phosphorylation of N-Sulfonylindoles under Mild Oxidative Conditions

Alkenylcarbyne Complexes Derived from the Reactions of OsXCl-(PPh3)(3) (X=H, Cl) with Propargyl Chloride and Phosphine Ligand-Controlled Transformation of Hydride-Carbyne to Carbene

Rhodium-Catalyzed beta-Selective Oxidative Heck-Type Coupling of Vinyl Acetate via C-H Activation

Rhodium-Catalyzed/Copper-Mediated Selective C2 Alkynylation of Indoles and C1 Alkynylation of Carbazoles with γ-Substituted tert-Propargyl Alcohols

Copper-Catalyzed Direct C2-Benzylation of Indoles with Alkylarenes

Construction of Isoquinolin-1(2H)-ones by Copper-Catalyzed Tandem Reactions of 2-(1-Alkynyl)benzaldimines with Water

Half-Sandwich B-Oxy Boratabenzene Ruthenium Complexes: Synthesis, Characterization, and Reactivity of (eta(6)-C5H5BOR)RuCl(PPh3)(2) (R = Et, Me)

Stabilizing two classical antiaromatic frameworks: Demonstration of photoacoustic imaging and the photothermal effect in metalla-aromatics

Highly active gold(I)-Silver(I) oxo cluster activating sp3 C-H bonds of methyl ketones under mild conditions

Rh(III)-catalyzed oxidative coupling of benzoic acids with geminal-substituted vinyl acetates: Synthesis of 3-substituted isocoumarins

Copper-catalyzed solvent-free redox condensation of benzothiazoles with aldehydes or benzylic alcohols

Conversion of a Hydrido-Butenylcarbyne Complex to eta(2)-Allene-Coordinated Complexes and Metallabenzenes

Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization

From osmium hydrido vinylidene to osmacycles: The key role of osmabutadiene intermediates

Synthesis and Organometallic Properties of Several Osmium Alkenylcarbyne Complexes

Stabilization of anti-aromatic and strained five-membered rings with a transition metal

A half-sandwich 1,2-azaborolyl ruthenium complex: Synthesis, characterization, and evaluation of its catalytic activities

A rhodamine-deoxylactam based sensor for chromo-fluorogenic detection of nerve agent simulant

pH-Switchable Inversion of the Metal-Centered Chirality of Metallabenzenes: Opposite Stereodynamics in Reactions of Ruthenabenzene with L- and D-Cysteine

cis-Dichloridotetrakis(trimethylphosphane-kappa P)ruthenium(II) benzene disolvate

Dimethyl (E)-2-(N-phenylacetamido)but-2-enedioate

Mononuclear Bis(imino)arylcopper(I) N-Heterocyclic Carbene Complex: Synthesis, Structure, and Reaction with Organic Azide

Synthesis, characterization, and electrochemical properties of bisosmabenzenes bridged by diisocyanides

C-H bond activation and subsequent C(sp2)-C(sp3) bond formation: Coupling of bromomethyl and triphenylphosphine in an iridium complex

Nucleophilic aromatic addition reactions of the metallabenzenes and metallapyridinium: Attacking aromatic metallacycles with bis(diphenylphosphino) methane to form metallacyclohexadienes and cyclic η2-allene- coordinated complexes

Synthesis of an osmafuran from photochemical hydrolysis of OsCl2(CH=C(PPh3)C(O)-eta(2)-CH=CH2)(PPh3)(2)

Visual and fluorogenic detection of a nerve agent simulant via a Lossen rearrangement of rhodamine-hydroxamate

Dichlorido(eta(4)-cycloocta-1,5-diene)bis(triphenylphosphine)osmium(II)

Selective synthesis of osmanaphthalene and osmanaphthalyne by intramolecular C-H activation

Osmapyridine and Osmapyridinium from a formal [4+2] cycloaddition reaction

Osmabenzenes from Osmacycles Containing an eta(2)-Coordinated Olefin

Synthesis, characterization and electrochemical properties of stable osmabenzenes containing PPh3 substituent

Nine-Membered osmacycles derived from metathesis reactionsbetween alkynes and an osmafuran

Synthesis of coordinated η2-α,β-unsaturated ketone osmacycles from an osmium-coordinated alkyne alcohol complex

Annulation of metallabenzenes: from osmabenzene to osmabenzothiazole to osmabenzoxazole

Formation of four conjugated osmacyclic species in a one-pot reaction

Synthesis and characterization of an air-stable p-osmaphenol

Synthesis and characterization of stable ruthenabenzenes starting from HCCCH(OH)CCH

Synthesis and characterization of a bimetallic iridium complex with a ten sp2-carbon chain bridge

Synthesis and characterization of stable ruthenabenzenes

Osmabenzenes from the reactions of HC CCH(OH)C CH with OsX2(PPh3)(3) (X = Cl, Br)