Tandem asymmetric dearomatized functionalization reaction of phenols with Evans-ynamides enabled by divergent electrophiles

Chiral Bronsted Acid-Catalyzed Asymmetric Reaction via Vinylidene <i>Ortho</i>-Quinone Methides

Mechanistic Insights into the Selective C-S Bond Formation by P450 TleB

Catalytic Epoxidation of Carbonyl Compounds via Carbonyl Ylides: from Racemic to Enantioselective

Reversal of regioselectivity in the chemistry of ynamides

Research Progress on the Hydroamination of <i>o</i>-Alkynylanilines for the Synthesis of Axially Chiral Indoles

Photo-Promoted Cascade Sigmatropic Rearrangement Reaction for the Synthesis of Polysubstituted 1,3-Conjugated Dienes

Copper-Catalyzed [2+2] Cyclization/Ring Expansion of Ene-Ynamides: Construction of Medium- and Large-Sized Rings

Enantioselective functionalization of unactivated C(sp<SUP>3</SUP>)-H bonds through copper-catalyzed diyne cyclization by kinetic resolution

A study on the application of discrete curvature feature extraction and optimization algorithms to battery health estimation

Gold Catalysis, Asymmetric Friedel-Crafts Alkylation Cascade for One-Pot Synthesis of Chiral Dihydrocarbazoles and Dihydrodibenzofurans

Organocatalytic Atroposelective Reactions of Alkynes

Nucleophile-Controlled Trapping of Gold Carbene by Nitriles and Water: Synthesis of 5<i>H</i>-Pyrimido[5,4-<i>b</i>]indoles and 2-Benzylidene-3-indolinones

Copper-catalyzed enantioselective desymmetrizing C(sp<SUP>2</SUP>)-H functionalization of azide-ynamides <i>via α</i>-imino copper carbenes

Outstanding reviewers for organic chemistry frontiers in 2023

Br?nsted-Acid-Catalyzed Enantioselective Desymmetrization of 1,3-Diols: Access to Chiral <i>β</i>-Amino Alcohol Derivatives

Recent advances in catalytic asymmetric Buchner reaction

Chiral Br?nsted acid-catalyzed asymmetric dearomative spirocyclization of alkynyl thioethers

Catalytic asymmetric reaction of isoxazoles and benzisoxazoles

Asymmetric formal C-C bond insertion into aldehydes via copper-catalyzed diyne cyclization

Bronsted Acid-Catalyzed Intramolecular Hydroalkoxylation/Claisen Rearrangement of Ynamides

Copper-catalyzed intermolecular formal (5?+?1) annulation of 1,5-diynes with 1,2,5-oxadiazoles

Asymmetric Metal Carbene <i>gem</i>-Dialkylation for the Construction of Chiral Quaternary Carbon Centers

Recent Advances in the Asymmetric Doyle-Kirmse Reaction

Recent advances in the construction of axially chiral arylpyrroles

Recent Advances in Asymmetric [1,2]-Stevens-Type Rearrangement via Metal Carbenes

Construction of Spirolactams by Unexpected Oxidative Cyclization of Alkenyl Diynes via Copper Catalysis

Bronste d acid-catalyze d asymmetric dearomatization of indolyl ynamides: practical and enantioselective synthesis of polycyclic indolines

Br?nsted acid-catalyzed asymmetric dearomatization for synthesis of chiral fused polycyclic enone and indoline scaffolds

Biocatalytic aminohydroxylation of styrenes for efficient synthesis of enantiopure beta-amino alcohols

Chiral Bronsted acid-catalyzed asymmetric intermolecular [4+2] annulation of ynamides with <i>para</i>-quinone methides

Construction of Axially Chiral Arylpyrroles via Atroposelective Diyne Cyclization

Lanthanide-oxo clusters for efficient catalytic reduction of carboxamides

Copper-Catalyzed Enantioselective Doyle-Kirmse Reaction of Azide-Ynamides via alpha-Imino Copper Carbenes

Organocatalytic intramolecular (4+2) annulation of enals with ynamides: atroposelective synthesis of axially chiral 7-aryl indolines

Controllable cyclization of alkynyl thioethers <i>via</i> Bronsted acid-catalyzed dearomatization

Enantioselective Desymmetrizing Hydroalkoxylation of 1,4-and 1,8-Diynes Enabled by Chiral Bronsted Acid Catalysis

Radical strategies for chemodivergent cyclization reactions

Copper-catalyzed atroposelective formal [4+1] annulation of 1,2-diketones with vinyl cations

Asymmetric Construction of 3-Aminoindoline Skeleton Bearing N-alpha-Quaternary Carbon Center

Research Progress on Enantioselective Desymmetrization Reactions Involving Metal Carbenes

Highly Site-Selective Oxidative Cyclization of Ene-ynamides via Non-Noble-Metal Catalysis: Access to Functionalized Lactams

Enantioselective Copper-Catalyzed Formal [2+1] and [4+1] Annulations of Diynes with Ketones via Carbonyl Ylides

Synthesis of Axially Chiral N-Arylindoles via Atroposelective Cyclization of Ynamides Catalyzed by Chiral Bronsted Acids

Catalyst-Dependent Stereospecific [3,3]-Sigmatropic Rearrangement of Sulfoxide-Ynamides: Divergent Synthesis of Chiral Medium-Sized N,S-Heterocycles

Metal-free dearomatization reactions of naphthol-ynamides for the divergent and enantioselective synthesis of azaspirocycles

Synthesis of Tetrahydroindole Derivatives via Metal-Free Intramolecular [4+2] Annulation of Ynamides

Enantioselective Rh-Catalyzed Azide-Internal-Alkyne Cycloaddition for the Construction of Axially Chiral 1,2,3-Triazoles

A copper-catalyzed B-H bond insertion reaction of azide-ynamide with borane adducts via alpha-imino copper carbenes

Efficient synthesis of tetracyclic gamma-lactams via gold-catalyzed oxidative cyclization of alkenyl diynes

Auxiliary-Free Remote Dearomatizative Nitrenoid Transfer for Enantioselective Construction of Spirolactams

Copper-Catalyzed Si-H Bond Insertion Reaction of N-Propargyl Ynamides with Hydrosilanes

Claisen Rearrangement Triggered by Bronsted Acid Catalyzed Alkyne Alkoxylation

Recent advances towards organocatalytic enantioselective desymmetrizing reactions

Thin-film temperature sensor made from particle-filled polymer-derived ceramics pyrolyzed in vacuum

I-2-Catalyzed Cycloisomerization of Ynamides: Chemoselective and Divergent Access to Indole Derivatives

Copper-Catalyzed Asymmetric Diyne Cyclization via [1,2]-Stevens-Type Rearrangement for the Synthesis of Chiral Chromeno[3,4-c]pyrroles

Claisen rearrangement triggered by transition metal-catalyzed alkyne alkoxylation

Asymmetric dearomatization catalysed by chiral Bronsted acids via activation of ynamides

Controllable synthesis of benzoxazinones and 2-hydroxy-3-indolinones by visible-light-promoted 5-endo-dig N-radical cyclization cascade

Copper-Catalyzed Cyclization of N-Propargyl Ynamides with Borane Adducts through B-H Bond Insertion

Recent Progress in the Gold-Catalyzed Annulations of Ynamides with Isoxazole Derivatives via alpha-Imino Gold Carbenes

Copper-catalyzed asymmetric cyclization of alkenyl diynes: method development and new mechanistic insights

Rapid and practical access to diverse quindolines by catalyst-free and regioselectivity-reversed Povarov reaction

Regio- and diastereoselective synthesis of trans-3,4-diaryldihydrocoumarins via metal-free [4+2] annulation of ynamides with o-hydroxybenzyl alcohols

Copper-Catalyzed C-H Bond and N-H Bond Insertion Reaction Based on Azide-Ynamide Cyclization

Recent advances towards catalytic asymmetric Conia-ene-type reactions

Regio- and Stereoselective Synthesis of Diverse 3,4-Dihydro-2-quinolones through Catalytic Hydrative Cyclization of Imine- and Carbonyl-Ynamides with Water

Gold-Catalyzed 1,1-Carboalkoxylation of Oxetane-Ynamides via Exocyclic Metal Carbenes: Divergent and Atom-Economical Synthesis of Tricyclic N-Heterocycles

Catalytic hydrative cyclization of aldehyde-ynamides with water for synthesis of medium-sized lactams

Unactivated C(sp(3))-H functionalization via vinyl cations

Bronsted Acid Catalyzed Dearomatization by Intramolecular Hydroalkoxylation/Claisen Rearrangement: Diastereo- and Enantioselective Synthesis of Spirolactams

Bronsted acid-mediated reactions of ynamides

Copper-CatalyzedCarbocyclization of Silyl Enol Ether Tethered Ynamides for Efficient and Practical Synthesis of2-Azabicyclo[3.2.0] Compounds(dagger)

Transition Metal-Catalyzed Tandem Reactions of Ynamides for Divergent N-Heterocycle Synthesis

One-pot synthesis of 2-hydroxymethylindoles: via photoredox-catalyzed ketyl-ynamide coupling/1,3-allylic alcohol transposition

Copper-catalyzed tandemcis-carbometallation/cyclization of imine-ynamides with arylboronic acids

Stereospecific access to bridged [n.2.1] skeletons through gold-catalyzed tandem reaction of indolyl homopropargyl amides

Copper-Catalyzed Asymmetric Reaction of Alkenyl Diynes with Styrenes by Formal [3+2] Cycloaddition via Cu-Containing AllCarbon 1,3-Dipoles: Access to Chiral Pyrrole-Fused Bridged [2.2.1] Skeletons

Synthesis of alpha-functionalized ketones by visible-light promoted oxygenation of alkenes

Efficient and Divergent Synthesis of Medium-Sized Lactams through Zinc-Catalyzed Oxidative Cyclization of Indoly Ynamides

Ynamide Smiles Rearrangement Triggered by Visible-Light-Mediated Regioselective Ketyl-Ynamide Coupling: Rapid Access to Functionalized Indoles and Isoquinolines

Facile Synthesis of alpha-Haloketones by Aerobic Oxidation of Olefins Using KX as Nonhazardous Halogen Source

Nitrene Transfer and Carbene Transfer in Gold Catalysis

Copper-Catalyzed Azide-Ynamide Cyclization to Generate alpha-Imino Copper Carbenes: Divergent and Enantioselective Access to Polycyclic N-Heterocycles

Radical Reactions of Ynamides

Synthesis of nitrogen-containing molecules via transition metal-catalyzed reactions on isoxazoles, anthranils and benzoisoxazoles

Recent Progress in the Copper-Catalyzed Cascade Cyclization Involving Intramolecular Hydroamination of Terminal Alkynes

Organocatalytic Enantioselective Conia-Ene-Type Carbocyclization of Ynamide Cyclohexanones: Regiodivergent Synthesis of Morphans and Normorphans

Stereoselective synthesis of 2,5-disubstituted pyrrolidines via gold-catalysed anti-Markovnikov hydroamination-initiated tandem reactions

Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement

Synthesis of functionalized 3-isochromanones via metal-free intramolecular alkoxylation-initiated cascade cyclization

1,4-Functionalization of 3-En-1-ynes with Alcohols via Zinc-Catalyzed Regioselective N-Oxide Oxidation

Synthesis of alpha-Halo Amides via Zinc-Mediated Tandem Oxidation/Halogenation of Ynamides

Metal-free alkene carbooxygenation following tandem intramolecular alkoxylation/Claisen rearrangement: stereocontrolled access to bridged [4.2.1] lactones

Ligand-free palladium catalyzed Ullmann biaryl synthesis: "household' reagents and mild reaction conditions

ASYMMETRIC CATALYSIS Chiral gamma-lactam synthesis via asymmetric C-H amidation

Generation of Endocyclic Vinyl Carbene Complexes via Gold-Catalyzed Oxidative Cyclization of Terminal Diynes: Toward Naphthoquinones and Carbazolequinones

NaBAr4F-Catalyzed Oxidative Cyclization of 1,5-and 1,6-Diynes: Efficient and Divergent Synthesis of Functionalized gamma- and delta-Lactams

Copper-Catalyzed Cascade Cyclization of Indolyl Homopropargyl Amides: Stereospecific Construction of Bridged Aza-[n.2.1] Skeletons

Reversal of Regioselectivity in Ynamide Chemistry

Generation of Donor/Donor Copper Carbenes through Copper-Catalyzed Diyne Cyclization: Enantioselective and Divergent Synthesis of Chiral Polycyclic Pyrroles

Zinc-Catalyzed Asymmetric Formal [4+3] Annulation of Isoxazoles with Enynol Ethers by 6 pi Electrocyclization: Stereoselective Access to 2H-Azepines

Synthesis of Isothiochroman-3-ones via Metal-Free Oxidative Cyclization of Alkynyl Thioethers

Benign catalysis with zinc: atom-economical and divergent synthesis of nitrogen heterocycles by formal [3+2] annulation of isoxazoles with ynol ethers

Gold-catalyzed cascade cyclization of: N -propargyl ynamides: Rapid access to functionalized indeno[1,2- c] pyrroles

Transition-metal-free oxidative cyclization of N-propargyl ynamides: stereospecific construction of linear polycyclic N-heterocycles

Zinc-catalyzed reaction of isoxazoles with thioynol ethers involving an unprecedented 1,2-sulfur migration

Facile synthesis of α-alkoxyl amides: Via scandium-catalyzed oxidative reaction between ynamides and alcohols

Synthesis of alpha-keto imides through copper-catalyzed oxidation of N-sulfonyl ynamides

Divergent synthesis of N-heterocycles via controllable cyclization of azido-diynes catalyzed by copper and gold

10.1039/c7ob01895arsc.li/obcRecent advances in transition-metal-catalyzed reactions of alkynes with isoxazoles

Yttrium-Catalyzed Tandem Intermolecular Hydroalkoxylation/Claisen Rearrangement

Gold-catalyzed intermolecular reaction of ynamides with 3-indolyl azides via an unexpected 1,2-alkyl migration

Synthesis of α,β-Unsaturated Amidines through Gold-Catalyzed Intermolecular Reaction of Azides with Ynamides

Dual gold/photoredox-catalyzed bis-arylative cyclization of chiral homopropargyl sulfonamides with diazonium salts: rapid access to enantioenriched 2,3-dihydropyrroles

Reversal of Regioselectivity in Catalytic Arene-Ynamide Cyclization: Direct Synthesis of Valuable Azepino[4,5-b]indoles and beta-Carbolines and DFT Calculations

Ring strain strategy for the control of regioselectivity. Gold-catalyzed anti-Markovnikov cycloisomerization initiated tandem reactions of alkynes

Yttrium-Catalyzed Intramolecular Hydroalkoxylation/Claisen Rearrangement Sequence: Efficient Synthesis of Medium-Sized Lactams

Recent advances in transition-metal-catalyzed reactions of alkynes with isoxazoles

Recent Advances in Dual Visible Light Photoredox and Gold-Catalyzed- Reactions

Recent progress towards gold-catalyzed synthesis of N-containing tricyclic compounds based on ynamides

Synthesis of Enantioenriched Pyrrolidines via Gold-Catalyzed Tandem Cycloisomerization/Hydrogenation of Chiral Homopropargyl Sulfonamides

Synthesis of 2-Aza-1,3-butadienes through Gold-Catalyzed Intermolecular Ynamide Amination/C-H Functionalization

Catalytic Ynamide Oxidation Strategy for the Preparation of α-Functionalized Amides

Gold-Catalyzed Intermolecular Ynamide Amination-Initiated Aza-Nazarov Cyclization: Access to Functionalized 2-Aminopyrroles

Recent Progress in the Metal-Free or Nonnoble-Metal-Catalyzed Oxidation of Alkynes by Using Pyridine N-Oxides as External Oxidants

Gold-Catalyzed Tandem Cycloisomerization-Halogenation of Chiral Homopropargyl Sulfonamides

Facile Synthesis of 2H-Pyrroles: Combination of Gold Catalysis and Lewis Acid Catalysis

Synthesis of fused isoquinolines via gold-catalyzed tandem alkyne amination/intramolecular O-H insertion

A zinc-catalyzed oxidative reaction of ynamides with phenols and thiophenols: highly site-selective synthesis of versatile alpha-aryloxy amides and alpha-arylthio amides

Highly Site Selective Formal [5+2] and [4+2] Annulations of Isoxazoles with Heterosubstituted Alkynes by Platinum Catalysis: Rapid Access to Functionalized 1,3-Oxazepines and 2,5-Dihydropyridines

Synthesis of alpha,beta-Unsaturated N-Sulfonyl Imides through Zinc-Catalyzed Intermolecular Oxidation of N-Sulfonyl Ynamides

Atom-Economic Synthesis of Fully Substituted 2-Aminopyrroles via Gold-Catalyzed Formal [3+2] Cycloaddition between Ynamides and Isoxazoles

Generation of alpha-Imin Gold Carbenes through Gold-Catalyzed Intermolecular Reaction of Azides with Ynamides

Recent Progress towards Transition-Metal-Catalyzed Synthesis of Fluorenes

Zinc-Catalyzed Alkyne Oxidation/C-H Functionalization: Highly Site-Selective Synthesis of Versatile Isoquinolones and β-Carbolines

Ylide formal [4 + 1] annulation

Atom-economic generation of gold carbenes: Gold-catalyzed formal [3+2] cycloaddition between ynamides and isoxazoles

Practical, modular, and general synthesis of 3-coumaranones through gold-catalyzed intermolecular alkyne oxidation strategy

Facile and efficient synthesis of [1,4]oxazino[3,2-b]indoles and 1H-pyrazino[2,3-b]indoles through gold-catalyzed cascade cyclization of (azido)ynamides

Generation of gold carbenes in water: Efficient intermolecular trapping of the α-oxo gold carbenoids by indoles and anilines

Flexible and practical synthesis of 3-oxyindoles through gold-catalyzed intermolecular oxidation of o-ethynylanilines

Highly diastereoselective synthesis of cyclopentenones via a one-pot gold catalysis, Nazarov cyclization and alkylation cascade

Gold-Catalyzed 6-Exo-Dig Cycloisomerization: A Versatile Approach to Functionalized Phenanthrenes

Recent progress towards transition metal-catalyzed synthesis of gamma-lactams

Gold-catalyzed intermolecular oxidation of chiral homopropargyl sulfonamides: a reliable access to enantioenriched pyrrolidin-3-ones

Gold-catalyzed tandem cycloisomerization and dimerization of chiral homopropargyl sulfonamides

Flexible and Practical Synthesis of Anthracenes through Gold-Catalyzed Cyclization of o-Alkynyldiarylmethanes

Gold-catalyzed oxidative cyclization of chiral homopropargyl amides: Synthesis of enantioenriched γ-lactams

Efficient Synthesis of gamma-Lactones via Gold-Catalyzed Tandem Cycloisomerization/Oxidation